The Structure of [Zn(bix) 2 (NO 3 ) 2 ]·4.5 H 2 O (bix = 1,4‐Bis(imidazol‐1‐ylmethyl)benzene): A New Type of Two‐Dimensional Polyrotaxane | Zendy

Hoskins Bernard F. | Zendy; Robson Richard | Zendy; Slizys Damian A. | Zendy

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The Structure of [Zn(bix) 2 (NO 3 ) 2 ]·4.5 H 2 O (bix = 1,4‐Bis(imidazol‐1‐ylmethyl)benzene): A New Type of Two‐Dimensional Polyrotaxane

Author(s) -

Hoskins Bernard F.,

Robson Richard,

Slizys Damian A.

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199723361

Subject(s) - crystallography , chemistry , benzene , rotaxane , stereochemistry , crystal structure , supramolecular chemistry , organic chemistry

Two independent and interpenetrating two‐dimensional networks , whose outstanding structural features are the polyrotaxane columns of the unprecedented type shown on the right, are found in the coordination polymer [Zn(bix) 2 (NO 3 ) 2 ]·4.5 H 2 O. This compound is only the third example of a 2‐D rotaxane; the other two were just recently reported.

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