An Organic Spin‐Ladder Molecular Material | Zendy

Rovira Concepció | Zendy; Veciana Jaume | Zendy; Ribera Elisabet | Zendy; Tarrés Judit | Zendy; Canadell Enric | Zendy; Rousseau Roger | Zendy; Mas Montserrat | Zendy; Molins Elies | Zendy; Almeida Manuel | Zendy; Henriques Rui T. | Zendy; Morgado Jorge | Zendy; Schoeffel JeanPhilippe | Zendy; Pouget JeanPaul | Zendy

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An Organic Spin‐Ladder Molecular Material

Author(s) -

Rovira Concepció,

Veciana Jaume,

Ribera Elisabet,

Tarrés Judit,

Canadell Enric,

Rousseau Roger,

Mas Montserrat,

Molins Elies,

Almeida Manuel,

Henriques Rui T.,

Morgado Jorge,

Schoeffel JeanPhilippe,

Pouget JeanPaul

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199723241

Subject(s) - tetrathiafulvalene , stack (abstract data type) , unpaired electron , spin (aerodynamics) , crystallography , molecule , electron , chemistry , condensed matter physics , organic molecules , materials science , physics , organic chemistry , quantum mechanics , computer science , thermodynamics , programming language

Pairs of stacks of organic donors D in the salt [(DT‐TTF) 2 ][Au(mnt) 2 ] (DT‐TTF = dithiophene‐tetrathiafulvalene, mnt = maleonitriledithiolate) form a classical ladder structure due to three close S … S interactions (see picture). Below 225 K the double stack of donor molecules forms a spin ladder with two legs, which arises through localization of unpaired electrons in the (DT‐TTF) 2 dimers.

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