Bimetallic Nanoparticle Catalysts Anchored Inside Mesoporous Silica | Zendy

Shephard Douglas S. | Zendy; Maschmeyer Thomas | Zendy; Johnson Brian F. G. | Zendy; Thomas John Meurig | Zendy; Sankar Gopinathan | Zendy; Ozkaya Dogan | Zendy; Zhou Wuzong | Zendy; Oldroyd Richard D. | Zendy; Bell Robert G. | Zendy

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Bimetallic Nanoparticle Catalysts Anchored Inside Mesoporous Silica

Author(s) -

Shephard Douglas S.,

Maschmeyer Thomas,

Johnson Brian F. G.,

Thomas John Meurig,

Sankar Gopinathan,

Ozkaya Dogan,

Zhou Wuzong,

Oldroyd Richard D.,

Bell Robert G.

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199722421

Subject(s) - bimetallic strip , catalysis , nanoparticle , thermal decomposition , mesoporous silica , mesoporous material , cluster (spacecraft) , extended x ray absorption fine structure , materials science , chemical engineering , silicate , mcm 41 , decomposition , particle (ecology) , nanotechnology , chemistry , organic chemistry , absorption spectroscopy , computer science , physics , quantum mechanics , engineering , programming language , oceanography , geology

A new hydrogenation catalyst is formed by thermolysis of the anionic carbonyl cluster [Ag 3 Ru 10 C 2 (CO) 28 Cl] 2− anchored to the mesoporous silicate MCM‐41. The cluster was isolated and characterized in MCM‐41 both before and after thermal treatment. The picture on the right shows a model, based in particular on EXAFS analysis, of the active bimetallic particle. The distribution of the Ag/Ru particles in the MCM‐41 cavities was determined by electron microscopy.

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