Anti‐Markovnikov Functionalization of Olefins: Rhodium‐Catalyzed Oxidative Aminations of Styrenes | Zendy

Beller Matthias | Zendy; Eichberger Martin | Zendy; Trauthwein Harald | Zendy

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Anti‐Markovnikov Functionalization of Olefins: Rhodium‐Catalyzed Oxidative Aminations of Styrenes

Author(s) -

Beller Matthias,

Eichberger Martin,

Trauthwein Harald

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199722251

Subject(s) - markovnikov's rule , amination , chemistry , rhodium , aryl , catalysis , alkyl , oxidative phosphorylation , olefin fiber , organic chemistry , surface modification , reductive amination , combinatorial chemistry , regioselectivity , biochemistry

Not the Markovnikov product 4 , but the anti‐Markovnikov product 3 is obtained by the oxidative amination of styrenes 1 with secondary amines 2 . The oxidant in this rhodium‐catalyzed reaction is the olefin itself, which is reduced to the ethylarene 5 . Ar = aryl, R = alkyl, aryl.

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