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Beltlike Aromatic Hydrocarbons by Metathesis Reaction with Tetradehydrodianthracene
Author(s) -
Kammermeier Stefan,
Jones Peter G.,
Herges Rainer
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199722001
Subject(s) - metathesis , conjugated system , substructure , salt metathesis reaction , materials science , computational chemistry , chemistry , nanotechnology , organic chemistry , engineering , polymer , polymerization , structural engineering
A substructure of a (5,5)‐armchair nanotube was obtained by metathesis reactions with tetradehydrodianthracene. The CC bonds in the product are all unsaturated and form a fully conjugated, beltlike system. A set of molecular building blocks can be used to synthesize other sections of nanotubes as well.