5,6,11,12,17,18‐Hexadehydro‐1,4,7,10,13,16‐hexaethynyltribenzo[ a,e,i ,]cyclododecene: Synthesis and CpCo‐Catalyzed Cycloisomerization to the First Superdelocalized Oligophenylenes | Zendy

Eickmeier Christian | Zendy; Junga Heiko | Zendy; Matzger Adam J. | Zendy; Scherhag Frank | Zendy; Shim Moonsub | Zendy; Vollhardt K. Peter C. | Zendy

Premium

5,6,11,12,17,18‐Hexadehydro‐1,4,7,10,13,16‐hexaethynyltribenzo[ a,e,i ,]cyclododecene: Synthesis and CpCo‐Catalyzed Cycloisomerization to the First Superdelocalized Oligophenylenes

Author(s) -

Eickmeier Christian,

Junga Heiko,

Matzger Adam J.,

Scherhag Frank,

Shim Moonsub,

Vollhardt K. Peter C.

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199721031

Subject(s) - cycloisomerization , catalysis , graphyne , stereochemistry , chemistry , organic chemistry , computational chemistry , density functional theory

The largest submit of the carbon allotrope “graphyne” , title compound 1 , is also a potential precursor to circular [6]phenylene, antikekulene. Single and double CpCo‐catalyzed cycloisomerization provided the respective angular [3]‐ and [5]phenylenes. Their spectroscopic data indicate that they harbor superdelocalization.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research