Clusters from Vertex‐ and Face‐Sharing Adamantane‐Like Units: A New Topology for Multinuclear Complexes | Zendy

Brechin Euan K. | Zendy; Harris Steven G. | Zendy; Parsons Simon | Zendy; Winpenny Richard E. P. | Zendy

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Clusters from Vertex‐ and Face‐Sharing Adamantane‐Like Units: A New Topology for Multinuclear Complexes

Author(s) -

Brechin Euan K.,

Harris Steven G.,

Parsons Simon,

Winpenny Richard E. P.

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199719671

Subject(s) - adamantane , homoleptic , vertex (graph theory) , nickel , metal , cobalt , topology (electrical circuits) , polyhedron , crystallography , chemistry , stereochemistry , materials science , combinatorics , inorganic chemistry , mathematics , organic chemistry , graph

Avoidance of a metal–metal bond is a significant factor favoring the formation of the nonanuclear cobalt complex [CO 9 (chp) 18 ] (framework depicted on the right; chp = 6‐chloro‐2‐pyridonate). The complex is homoleptic, which is unusual for 3d‐complexes of pyridonates, and this contrasts with the similar, but heteroleptic, nickel double adamantane frameworks also reported.

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