A Polyoxo–Polyolato Complex of Tantalum ( V ) with a Double Adamantane‐Like [Ta 7 O 12 ] 11+  Core | Zendy

Hegetschweiler Kaspar | Zendy; Raber Thomas | Zendy; Reiss Guido J. | Zendy; Frank Walter | Zendy; Wörle Michael | Zendy; Currao Antonio | Zendy; Nesper Reinhard | Zendy; Kradolfer Thomas | Zendy

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A Polyoxo–Polyolato Complex of Tantalum ( V ) with a Double Adamantane‐Like [Ta 7 O 12 ] 11+ Core

Author(s) -

Hegetschweiler Kaspar,

Raber Thomas,

Reiss Guido J.,

Frank Walter,

Wörle Michael,

Currao Antonio,

Nesper Reinhard,

Kradolfer Thomas

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199719641

Subject(s) - adamantane , diamondoid , polyoxometalate , octahedron , crystallography , tantalum , ligand (biochemistry) , chemistry , stereochemistry , ion , crystal structure , molecule , receptor , biochemistry , organic chemistry , catalysis

Only corner‐sharing between the seven TaO 6 octahedra is observed in the neutral complex [H −11 Ta 7 O 12 (tdci) 6 ] (tdci = 1,3,5‐trideoxy‐1,3,5‐tris(dimethylamino)‐ cis ‐inositol). The structure on the right (only one tdci ligand is illustrated) depicts the Ta 7 O 30 double adamantane core. In contrast to previously described structures of polyoxometalate ions, which have a predominantly edge‐shared framework, this compound has an unusually open structure.

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