Sn 6 (PR) 6 ], [Sn 3 (Pr) 2 , and [Cu 24 (PR) 12 ] (R = Triorganoisilyl): New Tin and Copper Phosphanediyl Clusters | Zendy

Driess Matthias | Zendy; Martin Stefan | Zendy; Merz Klaus | Zendy; Pintchouk Vassili | Zendy; Pritzkow Hans | Zendy; Grützmacher Hansjörg | Zendy; Kaupp Martin | Zendy

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Sn 6 (PR) 6 ], [Sn 3 (Pr) 2 , and [Cu 24 (PR) 12 ] (R = Triorganoisilyl): New Tin and Copper Phosphanediyl Clusters

Author(s) -

Driess Matthias,

Martin Stefan,

Merz Klaus,

Pintchouk Vassili,

Pritzkow Hans,

Grützmacher Hansjörg,

Kaupp Martin

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199718941

Subject(s) - tin , copper , transition metal , metal , crystallography , chemistry , materials science , inorganic chemistry , metallurgy , catalysis , organic chemistry

New structural motifs for main group or transition metal phosphanediyl clusters are obtained for the title compounds 1, 2 , and 3 . They are synthesized by complex Brønsted acid–base reactions of the corresponding primary silylphosphanes and inert stannanediyl derivatives or [{CuO t Bu} 4 ]. None of the three compounds needs terminal donor ligands on the metal centers to aid stability. R = triorganosilyl.

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