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[L 3 Ni(μ‐L) 3 NiL 3 ](AsF 6 ) 4 , (L NSF 2 NMe 2 ), a Dinuclear Nickel Complex with Bridging Thiazyl(dimethylamide)difluoride Ligands
Author(s) -
Behrens Ulrich,
Petersen Jan,
Lork Enno,
Watson Paul G.,
Mews Rüdiger
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199718781
Subject(s) - nickel , chemistry , bridging (networking) , crystallography , atom (system on chip) , organic chemistry , computer network , computer science , embedded system
The nickel atoms are triply bridged in [Ni 2 L 9 ] 4+ (L NSF 2 NMe 2 ), in which for the first time a nitrogen atom of a NS bond acts as a bridging ligand. The structure of the Ni 2 unit with all the coordinating N atoms is shown on the right.