Pyrazinedioxide–Tetracyanoethylene Arrays in the Solid State—New Donor–Acceptor Interaction for Crystal Engineering | Zendy

Greer Melinda L. | Zendy; McGee Byron J. | Zendy; Rogers Robin D. | Zendy; Blackstock Silas C. | Zendy

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Pyrazinedioxide–Tetracyanoethylene Arrays in the Solid State—New Donor–Acceptor Interaction for Crystal Engineering

Author(s) -

Greer Melinda L.,

McGee Byron J.,

Rogers Robin D.,

Blackstock Silas C.

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199718641

Subject(s) - tetracyanoethylene , solid state , acceptor , alkene , crystallography , crystallization , crystal (programming language) , crystal engineering , materials science , chemistry , crystal structure , photochemistry , physics , organic chemistry , supramolecular chemistry , condensed matter physics , computer science , programming language , catalysis

Ladder and web polymorphic forms of cocrystals of tetramethylpyrazinedioxide (TMPDO) and tetracyanoethylene (TCNE) are obtained by rapid or slow crystallization, respectively. In the thermodynamically less stable, purple (TMPDO) 2− TCNE crystals the donor and acceptor building blocks are linked through N + O − °C(alkene) interactions to form one‐dimensional ladders (see picture below).

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