Proton‐Dependent Monomer–Oligomer Interconversion of Metal Complexes | Zendy

Matsumoto Naohide | Zendy; Mizuguchi Yukiko | Zendy; Mago Genjin | Zendy; Eguchi Shingo | Zendy; Miyasaka Hitoshi | Zendy; Nakashima Toshio | Zendy; Tuchagues JeanPierre | Zendy

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Proton‐Dependent Monomer–Oligomer Interconversion of Metal Complexes

Author(s) -

Matsumoto Naohide,

Mizuguchi Yukiko,

Mago Genjin,

Eguchi Shingo,

Miyasaka Hitoshi,

Nakashima Toshio,

Tuchagues JeanPierre

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199718601

Subject(s) - random hexamer , oligomer , monomer , proton , chemistry , abstraction , metal , crystallography , photochemistry , polymer chemistry , polymer , organic chemistry , physics , quantum mechanics , philosophy , epistemology

The reversible reaction of a monomeric Cu II complex to a cyclic hexamer (crystal structures shown below) is the first example interconversion between a potential guest complex and a complex that cannot function as a guest [Eq. (a)]. It is—like in living organisms—controlled by a very common external signal, namely proton supply or abstraction.

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