Analysis of the Bonding in [Ni 5 (μ 5 ‐S)(μ 2 ‐SR) 5 ] − , an Unprecedented Pentanuclear Sulfide Cluster | Zendy

Cheung FuWah | Zendy; Lin Zhenyang | Zendy

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Analysis of the Bonding in [Ni 5 (μ 5 ‐S)(μ 2 ‐SR) 5 ] − , an Unprecedented Pentanuclear Sulfide Cluster

Author(s) -

Cheung FuWah,

Lin Zhenyang

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199718471

Subject(s) - cluster (spacecraft) , diagram , sulfide , crystallography , simple (philosophy) , physics , materials science , atomic physics , chemistry , computer science , metallurgy , philosophy , epistemology , database , programming language

contrary to the common belief that a simple description of the bonding in Ni–S(Se) clusters is not possible, the electronic structure of the cluster [Ni 5 S(S t Bu) 5 ] − ( 1 ) can be understood in terms of an idealized molecular orbital interaction diagram. The more complicated cluster [Ni 20 Se 12 (SeMe) 10 ] 2− can also be analyzed in this manner.

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