Coordination Arrays: Tetranuclear Cobalt( II ) Complexes with [2 × 2]‐Grid Structure | Zendy

Hanan Garry S. | Zendy; Volkmer Dirk | Zendy; Schubert Ulrich S. | Zendy; Lehn JeanMarie | Zendy; Baum Gerhard | Zendy; Fenske Dieter | Zendy

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Coordination Arrays: Tetranuclear Cobalt( II ) Complexes with [2 × 2]‐Grid Structure

Author(s) -

Hanan Garry S.,

Volkmer Dirk,

Schubert Ulrich S.,

Lehn JeanMarie,

Baum Gerhard,

Fenske Dieter

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199718421

Subject(s) - redox , cobalt , chemistry , crystallography , metal , ion , metal ions in aqueous solution , square tiling , electrochemistry , grid , stereochemistry , inorganic chemistry , electrode , organic chemistry , mathematics , geometry

The use of two tridentate ligands is the secret of success for the self‐assembly of structurally intriguing tetranuclear Co II complexes. The cation [Co 4 (L) 4 ] 8+ ( 1 ) exists as a [2 × 2]‐grid of octahedrally coordinated metal ions located at the corners of a square. The complex displays multiple redox processes and is of potential redox processes and is of potential interest for the development of electrochemically addressable inorganic arrays (R 1 , R 2 = H, Me; • = Co II ).

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