Evidence for Directed Metalation: A Structural Intermediate in the Formation of a Novel C‐bound Adenine Complex of Ruthenium | Zendy

Price Clayton | Zendy; Elsegood Mark R. J. | Zendy; Clegg William | Zendy; Rees Nicholas H. | Zendy; Houlton Andrew | Zendy

Premium

Evidence for Directed Metalation: A Structural Intermediate in the Formation of a Novel C‐bound Adenine Complex of Ruthenium

Author(s) -

Price Clayton,

Elsegood Mark R. J.,

Clegg William,

Rees Nicholas H.,

Houlton Andrew

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199717621

Subject(s) - nucleobase , ethylenediamine , metalation , chemistry , ruthenium , ligand (biochemistry) , denticity , stereochemistry , conjugate , combinatorial chemistry , crystallography , dna , crystal structure , catalysis , receptor , inorganic chemistry , organic chemistry , mathematics , biochemistry , mathematical analysis

The nucleobase–ligand conjugate from ethylenediamine and 9‐ethyladenine can function as a bidentate or tridentate ligand to Ru II . Both modes of coordination involve the ethylenediamine group, while the latter additionally relies on carbonmetal bond formation through C 8 of the nucleobase (structure depicted on the right).

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research