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Self‐Assembly of Convex and Concave Molecular Tectons to Form a Linear Molecular Array in the Solid State
Author(s) -
Hajek Frédérique,
Hosseini Mir Wais,
De Cian André,
Fischer Jean
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199717601
Subject(s) - schematic , solid state , regular polygon , fusion , representation (politics) , silicon , materials science , nanotechnology , chemistry , optoelectronics , mathematics , geometry , engineering , linguistics , philosophy , electronic engineering , politics , political science , law
A biconcave molecular module (koiland) was fashioned by the double fusion of two p ‐allylcalix[4]arenes through two silicon atoms. Koilands and linear molecular connectors self‐assemble to form an α‐network (koilate) in the solid state (see the schematic representation below).