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Intra‐Cavity Inclusion of [CpFe II (arene)] + Guests by Cyclotriveratrylene
Author(s) -
Holman K. Travis,
Atwood Jerry L.,
Steed Jonathan W.
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199717361
Subject(s) - stacking , chemistry , crystallography , crystal structure , inclusion (mineral) , stereochemistry , polar , organic chemistry , physics , mineralogy , astronomy
Polar one‐ and two‐dimensional stuctural motifs feature in the crystal structures of the inclusion complexes 1 between [CpFe II (arene)] + and the cryptophane cyclotriveratrylene. These structure result from π‐stacking interactions between the electron‐rich host and the electron‐deficient guest.