Novel Crown Ethers with a Trithiadiazapentalene–Trithiotriuret Redox System | Zendy

Graubaum Heinz | Zendy; Tittelbach Franz | Zendy; Lutze Gerhard | Zendy; Gloe Karsten | Zendy; Mackrodt Melinda | Zendy; Kuüger Torsten | Zendy; Krauss Norbert | Zendy; Deege Alfred | Zendy; Hinrichs Heike | Zendy

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Novel Crown Ethers with a Trithiadiazapentalene–Trithiotriuret Redox System

Author(s) -

Graubaum Heinz,

Tittelbach Franz,

Lutze Gerhard,

Gloe Karsten,

Mackrodt Melinda,

Kuüger Torsten,

Krauss Norbert,

Deege Alfred,

Hinrichs Heike

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199716481

Subject(s) - redox , crown (dentistry) , chemistry , polymer chemistry , materials science , organic chemistry , composite material

The differentiated recognition of Ag 1 and Hg 11 can be achieved with the pentaleno crown ethers 1 by variation of the cavity through the reversible trithia‐diazapentalene–trithiotriuret redox system ( 1⇌2) . These compounds were obtained in a one‐pot reaction of trithiadiazapentalenes with diamino polyethers of different chain lengths. n = 1–3, R = CH 3 , CH 2 C 6 H 5 .

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