Perfluoroalkyl‐Substituted Arylphosphanes as Ligands for Homogenous Catalysis in Supercritical Carbon Dioxide | Zendy

Kainz Sabine | Zendy; Koch Daniel | Zendy; Leitner Walter | Zendy; Baumann Wolfgang | Zendy

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Perfluoroalkyl‐Substituted Arylphosphanes as Ligands for Homogenous Catalysis in Supercritical Carbon Dioxide

Author(s) -

Kainz Sabine,

Koch Daniel,

Leitner Walter,

Baumann Wolfgang

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199716281

Subject(s) - supercritical carbon dioxide , solubility , supercritical fluid , homogeneous , catalysis , carbon dioxide , chemistry , homogeneous catalysis , organic chemistry , combinatorial chemistry , chemical engineering , thermodynamics , physics , engineering

The solubility of complexes is one decisive factor for their use as homogeneous catalysis in supercritical carbon dioxide (scCO 2 ). Complexes with perfluoroalkyl‐substituted arylphosphane ligands (shown schematically on the right), which can be prepared by a straightforward and variable synthetic methodology, exhibit high solubility in scCO 2 in contrast to unsubstituted parent compounds.

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