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Perfluoroalkyl‐Substituted Arylphosphanes as Ligands for Homogenous Catalysis in Supercritical Carbon Dioxide
Author(s) -
Kainz Sabine,
Koch Daniel,
Leitner Walter,
Baumann Wolfgang
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199716281
Subject(s) - supercritical carbon dioxide , solubility , supercritical fluid , homogeneous , catalysis , carbon dioxide , chemistry , homogeneous catalysis , organic chemistry , combinatorial chemistry , chemical engineering , thermodynamics , physics , engineering
The solubility of complexes is one decisive factor for their use as homogeneous catalysis in supercritical carbon dioxide (scCO 2 ). Complexes with perfluoroalkyl‐substituted arylphosphane ligands (shown schematically on the right), which can be prepared by a straightforward and variable synthetic methodology, exhibit high solubility in scCO 2 in contrast to unsubstituted parent compounds.