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Co 2 (O 3 PCH 2 PO 3 )·H 2 O: A Novel Microporous Diphosphonate with an Inorganic Framework and Hydrocarbon‐Lined Hydrophobic Channels
Author(s) -
Lohse Douglas L.,
Sevov Slavi C.
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199716191
Subject(s) - microporous material , octahedron , crystallography , tetrahedron , molecule , hydrocarbon , methylene , chemistry , materials science , inorganic chemistry , crystal structure , organic chemistry
Rectangular channels lined with methylene groups characterize the structure of the title compound. The framework is constructed from CoO 6 octahedra and CoO 4 tetrahedra that are linked through OPO bonds (structure depicted on the right). The hydrophobic channels appear suitable for the uptake of flat guest molecules.