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Superamolecular Self‐Recognition and Self‐Assembly in Gallium( III ) Catecholamide Triple Helices
Author(s) -
Caulder Dana L.,
Raymond Kenneth N.
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199714401
Subject(s) - triple helix , gallium , ligand (biochemistry) , chemistry , schematic , self assembly , ion , crystallography , methanol , metal ions in aqueous solution , stereochemistry , biochemistry , organic chemistry , receptor , engineering , electronic engineering
Remarkable ability for self‐recognition is displayed when a mixture of three different bis(catecholamide) ligands is allowed to react at room temperature with [Ga(acac) 3 ] and KOH in methanol (schematic representation below). These rigid, rodlike ligands differing only in the distance between the two coordination sites form M 2 L 3 triple helical complexes containing only one type of ligand with the trivalent metal ions M.

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