PS Ligands as Building Blocks of Chiral Dimetallatetrahedranes with a Common Vertex | Zendy

Scherer Otto J. | Zendy; Vondung Clemens | Zendy; Wolmershäuser Gotthelf | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

PS Ligands as Building Blocks of Chiral Dimetallatetrahedranes with a Common Vertex

Author(s) -

Scherer Otto J.,

Vondung Clemens,

Wolmershäuser Gotthelf

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199713031

Subject(s) - vertex (graph theory) , ligand (biochemistry) , tetragonal crystal system , chemistry , tungsten , cluster (spacecraft) , stereochemistry , crystallography , combinatorics , mathematics , crystal structure , organic chemistry , computer science , receptor , graph , biochemistry , programming language

A cluster with two chiral tetrahedrane fragments , which are linked through a common tungsten vertex ( 2 ), is formed on heating the tetragonal‐pyramidal trinuclear complex 1 with two μ 3 PS ligands (Cp 4 C 5 H i Pr 4 ). The terminally coordinated PS ligand in 1 is therefore converted into a doubly side‐on bound μ‐η 2 :η 2 ‐PS ligand.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research