Quasi‐Complete Solvation of Organic Molecules in the Crystalline State | Zendy

Shivanyuk Alexander | Zendy; Böhmer Volker | Zendy; Vogt Walter | Zendy; Paulus Erich F. | Zendy

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Quasi‐Complete Solvation of Organic Molecules in the Crystalline State

Author(s) -

Shivanyuk Alexander,

Böhmer Volker,

Vogt Walter,

Paulus Erich F.

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199713011

Subject(s) - solvation , dimethyl sulfoxide , pyridine , molecule , hydrogen bond , solvent , chemistry , sulfoxide , hydrogen , crystallography , solid state , computational chemistry , materials science , organic chemistry

The maximum possible number of hydrogen bonds to the solvent are formed by the resorcarene 1 in crystals of 1 · 18 DMSO (DMSO = dimethyl sulfoxide). Whereas highly solvated, discrete molecules of 1 are found in 1 · 18 DMSO, hydrogen‐bonded, infinite columns of 1 that are entirely wrapped by layers of pyridine molecules are present in crystals of the composition 1 · 14 pyridine.

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