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Quasi‐Complete Solvation of Organic Molecules in the Crystalline State
Author(s) -
Shivanyuk Alexander,
Böhmer Volker,
Vogt Walter,
Paulus Erich F.
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199713011
Subject(s) - solvation , dimethyl sulfoxide , pyridine , molecule , hydrogen bond , solvent , chemistry , sulfoxide , hydrogen , crystallography , solid state , computational chemistry , materials science , organic chemistry
The maximum possible number of hydrogen bonds to the solvent are formed by the resorcarene 1 in crystals of 1 · 18 DMSO (DMSO = dimethyl sulfoxide). Whereas highly solvated, discrete molecules of 1 are found in 1 · 18 DMSO, hydrogen‐bonded, infinite columns of 1 that are entirely wrapped by layers of pyridine molecules are present in crystals of the composition 1 · 14 pyridine.