Enantioselective Formation of Double and Triple Helicates of Silver( I ): The Role of Stacking Interactions | Zendy

Provent Christophe | Zendy; Hewage Sujatha | Zendy; Brand Guy | Zendy; Charbonnière Loïc J. | Zendy; Williams Alan F. | Zendy; Bernardinelli Gérald | Zendy

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Enantioselective Formation of Double and Triple Helicates of Silver( I ): The Role of Stacking Interactions

Author(s) -

Provent Christophe,

Hewage Sujatha,

Brand Guy,

Charbonnière Loïc J.,

Williams Alan F.,

Bernardinelli Gérald

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199712871

Subject(s) - stacking , enantioselective synthesis , chirality (physics) , stereochemistry , ligand (biochemistry) , chemistry , crystallography , physics , receptor , catalysis , chiral symmetry , organic chemistry , biochemistry , quantum mechanics , nambu–jona lasinio model , quark

Despite having ligands with almost identical conformations , the structures of the Ag I complexes of 1 and 2 differ significantly: ligand 1 forms a double‐helical complex of P chirality, and 2 gives a triple‐helical complex (depicted on the right). The reason for the difference appears to be the existence of strong interligand stacking in the latter case.

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