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A Convenient Way to Novel Fe IV Complexes with Mixed N/S/P Coordination Spheres and “Innocent” Ligands
Author(s) -
Sellmann Dieter,
Emig Susanne,
Heinemann Frank W.,
Knoch Falk
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199712011
Subject(s) - coordination sphere , lone pair , amide , ligand (biochemistry) , chemistry , crystallography , metal , coordination complex , electron , character (mathematics) , spheres , stereochemistry , molecule , crystal structure , physics , organic chemistry , biochemistry , receptor , quantum mechanics , geometry , mathematics , astronomy
A simple one‐pot reaction with readily accessible compounds [Eq. (a)] provides a route to high‐valent molecular Fe IV complexes with a N/S/P coordination sphere. The Fe IV character of the metal center, which is stabilized by π‐donor bonds from the lone pairs of electrons of the amide N and thiolate S donors, is confirmed by spectroscopic and structural data of 1 (R n Pr). The L 4− ligand is “innocent”!
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