Synthesis and Characterization of the Carbide Cubane Cluster [Fe 3 (CO) 9 Te 4 (μ 3 ‐CTeBr 4 )] with an Unusual Tetrahedral CTe 4  Unit | Zendy

Eveland Jeffrey R. | Zendy; Whitmire Kenton H. | Zendy

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Synthesis and Characterization of the Carbide Cubane Cluster [Fe 3 (CO) 9 Te 4 (μ 3 ‐CTeBr 4 )] with an Unusual Tetrahedral CTe 4 Unit

Author(s) -

Eveland Jeffrey R.,

Whitmire Kenton H.

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199711931

Subject(s) - cubane , cluster (spacecraft) , tetrahedron , carbide , characterization (materials science) , crystallography , solid state , carbon fibers , decomposition , materials science , chemistry , crystal structure , nanotechnology , metallurgy , computer science , organic chemistry , composite number , composite material , programming language

A carbide carbon atom as a vertex stabilized by coordination to the Lewis acid TeBr 4 is a feature of the cubane‐like cluster 1 shown on the right. This complex, which is indefinitely stable in the solid state but dissolves only in DMSO—and then with rapid decomposition—is the ultimate product in the reaction between [Te 2 Fe 3 (CO) 9 ] and CBr 4 .

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