Formation of Isobenzenes by Thermal Isomerization of 1,3‐hexadiene‐5‐yne Derivatives | Zendy

Hopf Henning | Zendy; Berger Harald | Zendy; Zimmermann Gerhard | Zendy; Nüchter Uta | Zendy; Jones Peter G. | Zendy; Dix Ina | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Formation of Isobenzenes by Thermal Isomerization of 1,3‐hexadiene‐5‐yne Derivatives

Author(s) -

Hopf Henning,

Berger Harald,

Zimmermann Gerhard,

Nüchter Uta,

Jones Peter G.,

Dix Ina

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199711871

Subject(s) - isomerization , aromatization , benzene , chemistry , photochemistry , trapping , styrene , pyrolysis , medicinal chemistry , organic chemistry , catalysis , polymer , ecology , copolymer , biology

Prototype of a new aromatization reaction : thermal rearrangement of 1,3‐hexadiene‐5‐yne ( 1 ) to benzene ( 3 ) via isobenzene 2 , a highly reactive benezene isomer. Trapping experiments with styrene and the behavior of arenes containing 1 as a subunit indicate that this isomerization is also suitable for preparing condensed arenes and fullerene fragments.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research