The[Cu 2 (O 2 CMe) 4 (H 2 O) 2 ]/(py) 2 CO System as the Source of an Unusual Heptanuclear Complex and a Novel Dodecanclear “Flywheel” Cluster | Zendy

Tangoulis Vasilis | Zendy; Raptopoulou Catherine P. | Zendy; Paschalidou Sofia | Zendy; Bakalbassis Evangelos G. | Zendy; Perlepes Spyros P. | Zendy; Terzis Aris | Zendy

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The[Cu 2 (O 2 CMe) 4 (H 2 O) 2 ]/(py) 2 CO System as the Source of an Unusual Heptanuclear Complex and a Novel Dodecanclear “Flywheel” Cluster

Author(s) -

Tangoulis Vasilis,

Raptopoulou Catherine P.,

Paschalidou Sofia,

Bakalbassis Evangelos G.,

Perlepes Spyros P.,

Terzis Aris

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199710831

Subject(s) - tetrahedron , cluster (spacecraft) , chemistry , crystallography , copper , vertex (graph theory) , magnetic susceptibility , ground state , stereochemistry , physics , combinatorics , computer science , atomic physics , mathematics , organic chemistry , graph , programming language

A chair‐within‐a‐chair arrangement of the twelve copper atoms (bottom left) is characteristic of one of the complexes reported here; the other complex features two Cu tetrahedra sharing a common vertex (bottom right). Both were isolated from the reaction mixture [Cu 2 (O 2 CMe) 4 (H 2 O) 2 ]/(py) 2 CO in MeCN. Magnetic susceptibility data show that the heptanuclear complex has an S = 1/2 ground state.

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