Novel Clusters of Transition Metals and Main Group Oxides in the Alkylamine/Oxovanadium/Borate System | Zendy

Rijssenbeek Job T. | Zendy; Rose David J. | Zendy; Haushalter Robert C. | Zendy; Zubieta Jon | Zendy

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Novel Clusters of Transition Metals and Main Group Oxides in the Alkylamine/Oxovanadium/Borate System

Author(s) -

Rijssenbeek Job T.,

Rose David J.,

Haushalter Robert C.,

Zubieta Jon

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199710081

Subject(s) - boron , transition metal , vanadium , chemistry , ethylenediamine , denticity , group (periodic table) , crystallization , inorganic chemistry , metal , crystallography , organic chemistry , catalysis

Unprecedented structural and compositional features are exhibited by these large vanadium borate clusters (for example 1 , see picture on the right). Facile solubilization and crystallization of transition metal oxides by these large, multidentate polyborate ligands portends a rich and diverse chemistry for transition element/polyborate clusters. en = ethylenediamine.

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