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Novel Clusters of Transition Metals and Main Group Oxides in the Alkylamine/Oxovanadium/Borate System
Author(s) -
Rijssenbeek Job T.,
Rose David J.,
Haushalter Robert C.,
Zubieta Jon
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199710081
Subject(s) - boron , transition metal , vanadium , chemistry , ethylenediamine , denticity , group (periodic table) , crystallization , inorganic chemistry , metal , crystallography , organic chemistry , catalysis
Unprecedented structural and compositional features are exhibited by these large vanadium borate clusters (for example 1 , see picture on the right). Facile solubilization and crystallization of transition metal oxides by these large, multidentate polyborate ligands portends a rich and diverse chemistry for transition element/polyborate clusters. en = ethylenediamine.