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Hydrothermal Synthesis of Microporous Transition Metal Squarates: Preparation and Structure of [CO 3 (μ 3 ‐OH) 2 (C 4 O 4 ) 2 ]·3H 2 O
Author(s) -
Gutschke Siegfried O. H.,
Molinier Michel,
Powell Annie K.,
Wood Paul T.
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199709911
Subject(s) - microporous material , hydroxide , hydrothermal circulation , cobalt hydroxide , cobalt , transition metal , hydrothermal synthesis , materials science , metal , metal hydroxide , crystallography , inorganic chemistry , chemistry , chemical engineering , organic chemistry , metallurgy , catalysis , electrode , electrochemistry , engineering , composite material
A cobalt hydroxide backbone with a structure reminiscent of that found in cobalt( II ) hydroxide forms the basis of the framework of the title compound. The squarate ligands of this coordination solid link the metal hydroxide strips together and form the walls of channels with a diameter of approximately 7 Å.