Premium
Zirconocen–Benzyme‐Mediated Intramolecular Coupling of Bis(alkynyl)phosphane: A Way to Mono‐ and Tricyclic 1,2‐Dihydrophosphetes
Author(s) -
Dupuis Laurence,
Pirio Nadine,
Meunier Philippe,
Igau Alain,
Donnadieu Bruno,
Majoral JeanPierre
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199709871
Subject(s) - tricyclic , aryne , intramolecular force , chemistry , coupling (piping) , zirconium , medicinal chemistry , stereochemistry , organic chemistry , materials science , metallurgy
The tricyclic zirconium complex 2 is formed when transient zirconocene–benzyne is allowed to react with bis(alkynyl)phosphane 1 . Further reactions with 2 lead to mono‐ and tricyclic 1,2‐dihydrophosphetes.