[H 3 N(CH 2 ) 2 NH 3 ]       0.5    2+    [Sn 4 P 3 O 12 ] − : An Open‐Framework Tin( II ) Phosphate | Zendy

Natarajan Srinivasan | Zendy; Attfield Martin P. | Zendy; Cheetham Anthony K. | Zendy

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[H 3 N(CH 2 ) 2 NH 3 ] 0.5 2+ [Sn 4 P 3 O 12 ] − : An Open‐Framework Tin( II ) Phosphate

Author(s) -

Natarajan Srinivasan,

Attfield Martin P.,

Cheetham Anthony K.

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199709781

Subject(s) - ring (chemistry) , ethylenediamine , crystallography , lone pair , tetrahedron , group (periodic table) , stereochemistry , physics , chemistry , molecule , inorganic chemistry , organic chemistry , quantum mechanics

Colorless en ‐SnPO‐1, the title compound , crystallizes in the space group Pnaa and forms a network of alternating pyramidal SnO 3 and tetrahedral PO 4 moieties in which all the vertices are shared. The structure‐directing agent, diprotonated ethylenediamine, is located in an eight‐ring channel system. The Sn II lone pairs protrude into a second channel system comprising squashed twenty‐rings (see picture).

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