Supramolecular Isomerism in Coordination Polymers: Conformational Freedom of Ligands in [Co(NO 3 ) 2 (1,2‐bis(4‐pyridyl)ethane) 1.5 ]  n | Zendy

Hennigar Tracy L. | Zendy; MacQuarrie Donald C. | Zendy; Losier Pierre | Zendy; Rogers Robin D. | Zendy; Zaworotko Michael J. | Zendy

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Supramolecular Isomerism in Coordination Polymers: Conformational Freedom of Ligands in [Co(NO 3 ) 2 (1,2‐bis(4‐pyridyl)ethane) 1.5 ] n

Author(s) -

Hennigar Tracy L.,

MacQuarrie Donald C.,

Losier Pierre,

Rogers Robin D.,

Zaworotko Michael J.

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199709721

Subject(s) - supramolecular chemistry , crystallography , polymer , chemistry , supramolecular polymers , bilayer , crystallization , stereochemistry , crystal structure , membrane , organic chemistry , biochemistry

Bilayers or open‐framework ladder structure? Which supramolecular isomer is formed from Co(NO 3 ) 2 and the nonrigid spacer 1,2‐bis(2‐pyridyl)ethane depends on the crystallization conditions. The open‐framework coordination polymer contains large, square cavities of 10 × 10 Å. A section of the bilayer motif is shown on the right.

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