Crystal Engineering of Melamine–Imide Complexes; Tuning the Stoichiometry by Steric Hindrance of the Imide Carbonyl Groups | Zendy

Lange Ronald F. M. | Zendy; Beijer Felix H. | Zendy; Sijbesma Rint P. | Zendy; Hooft Rob W. W. | Zendy; Kooijman Huub | Zendy; Spek Anthony L. | Zendy; Kroon Jan | Zendy; Meijer E. W. | Zendy

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Crystal Engineering of Melamine–Imide Complexes; Tuning the Stoichiometry by Steric Hindrance of the Imide Carbonyl Groups

Author(s) -

Lange Ronald F. M.,

Beijer Felix H.,

Sijbesma Rint P.,

Hooft Rob W. W.,

Kooijman Huub,

Spek Anthony L.,

Kroon Jan,

Meijer E. W.

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199709691

Subject(s) - imide , steric effects , melamine , succinimide , chemistry , hydrogen bond , polymer chemistry , stoichiometry , crystal structure , organic chemistry , molecule

A defined melamine–imide ratio in cocrystals can be selected by changing the steric hindrance around the hydrogen‐bond acceptor sites of the imides. Crystalline 1:1, 1:2, and 1:3 complexes of melamine may thus be obtained with succinimide, glutarimide, and 1‐ N ‐propylthymine (see picture), respectively.

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