Helical, Polymeric Chains in Crystalline Gallaborane [GaBH 6 ] n  at 110 K | Zendy

Downs Anthony J. | Zendy; Parsons Simon | Zendy; Pulham Colin R. | Zendy; Souter Philip F. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Helical, Polymeric Chains in Crystalline Gallaborane [GaBH 6 ] n at 110 K

Author(s) -

Downs Anthony J.,

Parsons Simon,

Pulham Colin R.,

Souter Philip F.

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199708901

Subject(s) - tetrahedron , crystallography , bridging (networking) , materials science , group (periodic table) , chemistry , organic chemistry , computer science , computer network

Distorted tetrahedral GaH 4 and tetrahedral BH 4 moieties are the building blocks of the helical, polymeric chains formed by gallaborane at 110 K (schematically shown on the right). There are two distinct types of BH 4 groups: one is involved in Ga(μ‐H) 2 B coordination and the other in unusual monohydrogen bridging of two adjacent GaH 2 units. The structure invites comparison with those of other main group hydrides.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research