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The First Transition Metal Complex of a Silaborane
Author(s) -
Wesemann Lars,
Ramjoie Yves,
Ganter Beate,
Wrackmeyer Bernd
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199708881
Subject(s) - deprotonation , yield (engineering) , transition metal , chemistry , salt (chemistry) , motif (music) , metal , structural motif , crystallography , ion , stereochemistry , materials science , physics , organic chemistry , metallurgy , catalysis , biochemistry , acoustics
An unprecedented structural motif for metallaboranes is exhibited by the anion [{HFe(MeSiB 10 H 10 )} 2 ] 2− (see picture), which was isolated as the { n Bu 4 N} 2 salt in 63% yield from the reaction of deprotonated sila‐ nido ‐undecaborate and FeBr 2 .
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