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Studies of the First S‐Position Isomer of Bis(ethylenedithio)tetrathiafulvalene
Author(s) -
Hudhomme Piétrick,
Blanchard Philippe,
Sallé Marc,
Le Moustarder Soazig,
Riou Amédée,
Jubault Michel,
Gorgues Alain,
Duguay Guy
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199708781
Subject(s) - tetrathiafulvalene , chemistry , sulfur , planar , superconductivity , crystallography , core (optical fiber) , radical ion , stereochemistry , molecule , materials science , organic chemistry , ion , condensed matter physics , physics , computer science , computer graphics (images) , composite material
Worthwhile goals for the synthesis of conducting materials are compounds 1–3 , which contain the tetrathiafulvalene (TTF) framework. Compound 1 and a bis(methylsulfanyl) analogue have now been synthesized. Their oxidation behavior resembles that of the title compound, whose cation‐radical salts are superconductors. The TTF core of these systems is essentially planar, and the outer sulfur atoms play a role in the crystallographic network.