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β‐Cyclodextrin‐Modified Diphosphanes as Ligands for Supramolecular Rhodium Catalysts
Author(s) -
Reetz Manfred T.,
Waldvogel Siegfried R.
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199708651
Subject(s) - rhodium , hydroformylation , catalysis , cyclodextrin , supramolecular chemistry , chemistry , transition metal , polymer chemistry , organic chemistry , combinatorial chemistry , molecule
Hydrogenation and hydroformylation occur highly selectively with rhodium complexes of β‐cyclodextrin‐modified phosphanes (such as 1 ) as catalysts. These are of interest particularly for industrial applications, in which transition‐metal catalysis and phase‐transfer catalysis are combined in one and the same catalyst.

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