Premium
Reduction of Dicarbapentaboranes(5) to 1,2‐Diborata‐4‐boracyclopentadienes: Antiaromatic Compounds with 4π‐Electron Systems
Author(s) -
Unverzagt Markus,
Winkler HeinzJürgen,
Brock Michael,
Hofmann Matthias,
von Ragué Schleyer Paul,
Massa Werner,
Berndt Armin
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199708531
Subject(s) - antiaromaticity , reduction (mathematics) , tetragonal crystal system , electron , chemistry , computational chemistry , crystallography , aromaticity , physics , mathematics , organic chemistry , crystal structure , geometry , quantum mechanics , molecule
Instead of tetragonal pyramids like 1 , the antiaromatic 1,2‐diborata‐4‐boracyclopentadiene five‐membered rings 3 are formed on two‐electron reduction of dicarbapentaboranes(5) 2 .