Reduction of Dicarbapentaboranes(5) to 1,2‐Diborata‐4‐boracyclopentadienes: Antiaromatic Compounds with 4π‐Electron Systems | Zendy

Unverzagt Markus | Zendy; Winkler HeinzJürgen | Zendy; Brock Michael | Zendy; Hofmann Matthias | Zendy; von Ragué Schleyer Paul | Zendy; Massa Werner | Zendy; Berndt Armin | Zendy

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Reduction of Dicarbapentaboranes(5) to 1,2‐Diborata‐4‐boracyclopentadienes: Antiaromatic Compounds with 4π‐Electron Systems

Author(s) -

Unverzagt Markus,

Winkler HeinzJürgen,

Brock Michael,

Hofmann Matthias,

von Ragué Schleyer Paul,

Massa Werner,

Berndt Armin

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199708531

Subject(s) - antiaromaticity , reduction (mathematics) , tetragonal crystal system , electron , chemistry , computational chemistry , crystallography , aromaticity , physics , mathematics , organic chemistry , crystal structure , geometry , quantum mechanics , molecule

Instead of tetragonal pyramids like 1 , the antiaromatic 1,2‐diborata‐4‐boracyclopentadiene five‐membered rings 3 are formed on two‐electron reduction of dicarbapentaboranes(5) 2 .

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