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Chemical Selection and Self‐Assembly in a Cyclization Reaction
Author(s) -
Rudkevich Dmitry M.,
Rebek Julius
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199708461
Subject(s) - reactivity (psychology) , chemistry , ring (chemistry) , hydrogen bond , self assembly , selection (genetic algorithm) , combinatorial chemistry , stereochemistry , molecule , organic chemistry , computer science , artificial intelligence , medicine , alternative medicine , pathology
Self‐help : A reaction product recognizes a stable intermediate and channels its reactivity to the formation of an eleven‐membered ring (see below). A template effect is proposed, which involves molecular recognition through hydrogen bonding. PFP = pentafluorophenyl.
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