Asymmetric Dihydroxylation with MeO‐Polyethyleneglycol‐Bound Ligands | Zendy

Bolm Carsten | Zendy; Gerlach Arne | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Asymmetric Dihydroxylation with MeO‐Polyethyleneglycol‐Bound Ligands

Author(s) -

Bolm Carsten,

Gerlach Arne

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199707411

Subject(s) - dihydroxylation , ligand (biochemistry) , homogeneous , catalysis , chemistry , homogeneous catalysis , metal , organic chemistry , combinatorial chemistry , stereochemistry , enantioselective synthesis , biochemistry , mathematics , receptor , combinatorics

Homogenous catalysis as long as it is needed : the advantages of homogeneous and heterogeneous metal catalysis can be combined by attachment of an alkaloid ligand to polyethyleneglycol methylmonoether. Diols with up to 99% ee have been obtained in the asymmetric Sharpless dihydroxylation of olefins with the polymer modified ligand 1 (DHQD = dihydroquinidine).

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research