[(CF 3 ) 2 Hg(μ‐F) 2 Hg(CF 3 ) 2 ] 2− : Synthesis, Structure, and Reactivity | Zendy

Viets Detlef | Zendy; Lork Enno | Zendy; Watson Paul G. | Zendy; Mews Rüdiger | Zendy

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[(CF 3 ) 2 Hg(μ‐F) 2 Hg(CF 3 ) 2 ] 2− : Synthesis, Structure, and Reactivity

Author(s) -

Viets Detlef,

Lork Enno,

Watson Paul G.,

Mews Rüdiger

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199706231

Subject(s) - chemistry , reactivity (psychology) , crystal structure , reagent , nucleophile , fluoride , crystallography , inorganic chemistry , organic chemistry , medicine , alternative medicine , pathology , catalysis

The first anionic fluoromercury complex [(CF 3 ) 2 Hg‐(μ‐F) 2 Hg(CF 3 ) 2 ] 2− was prepared from Hg(CF 3 ) 2 and TAS fluoride (Me 2 N) 3 S + (Me 3 Si)F 2 − , and characterized by X‐ray crystal structure analysis (structure depicted on the right). In contrast to the neutral compound, the anions can be used as nucleophilic CF 3 ‐transfer reagents.

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