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[(CF 3 ) 2 Hg(μ‐F) 2 Hg(CF 3 ) 2 ] 2− : Synthesis, Structure, and Reactivity
Author(s) -
Viets Detlef,
Lork Enno,
Watson Paul G.,
Mews Rüdiger
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199706231
Subject(s) - chemistry , reactivity (psychology) , crystal structure , reagent , nucleophile , fluoride , crystallography , inorganic chemistry , organic chemistry , medicine , alternative medicine , pathology , catalysis
The first anionic fluoromercury complex [(CF 3 ) 2 Hg‐(μ‐F) 2 Hg(CF 3 ) 2 ] 2− was prepared from Hg(CF 3 ) 2 and TAS fluoride (Me 2 N) 3 S + (Me 3 Si)F 2 − , and characterized by X‐ray crystal structure analysis (structure depicted on the right). In contrast to the neutral compound, the anions can be used as nucleophilic CF 3 ‐transfer reagents.