Oligo(ethylenoxy)oxy‐Bridged Stilbenes as Ligands for σ‐ and π‐Coordinated Ag +  and Na +  Ions | Zendy

Futterer Thomas | Zendy; Merz Andreas | Zendy; Lex Johann | Zendy

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Oligo(ethylenoxy)oxy‐Bridged Stilbenes as Ligands for σ‐ and π‐Coordinated Ag + and Na + Ions

Author(s) -

Futterer Thomas,

Merz Andreas,

Lex Johann

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199706111

Subject(s) - chemistry , ion , crystallography , ether , crown ether , oxygen atom , bond length , stereochemistry , inorganic chemistry , molecule , crystal structure , organic chemistry

Four oxygen atoms and a double bond , coordinate to the Ag + ion in the complex with the stilbene crown ether 1 . Surprisingly, the Na + ion is also complexed by 1 in a similar geometry. The coordinative bond between a Na + ion and a π bond, which is detected here for the first time, is probably induced and supported by the oligo(ethylenoxy)oxy bridge. M + X − AgNO 3 , NaClO 4 .

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