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Synthesis and Resolution of the Configurationally Stable Tris(tetrachlorobenzenediolato)phosphate( V ) Ion
Author(s) -
Lacour Jérǒ;me,
Ginglinger Catherine,
Grivet Chantal,
Bernardinelli Gérald
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199706081
Subject(s) - enantiopure drug , tris , enantiomer , resolution (logic) , phosphate , ion , chemistry , salt (chemistry) , octahedron , stereochemistry , crystallography , enantioselective synthesis , organic chemistry , biochemistry , computer science , catalysis , artificial intelligence
Easily accessible and configurationally stable are words that describe the enantiopure tris(tetrachlorobenzenediolato)phosphate( V ) ion ( 1 ). These qualities predetermine 1 for use in enantiomeric resolution and asymmetric synthesis. X‐ray structure analysis of the cinchonidinium salt of 1 confirmed the octahedral geometry and provided the absolute configuration of the anion.