Synthesis and Resolution of the Configurationally Stable Tris(tetrachlorobenzenediolato)phosphate( V ) Ion | Zendy

Lacour Jérǒ;me | Zendy; Ginglinger Catherine | Zendy; Grivet Chantal | Zendy; Bernardinelli Gérald | Zendy

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Synthesis and Resolution of the Configurationally Stable Tris(tetrachlorobenzenediolato)phosphate( V ) Ion

Author(s) -

Lacour Jérǒ;me,

Ginglinger Catherine,

Grivet Chantal,

Bernardinelli Gérald

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199706081

Subject(s) - enantiopure drug , tris , enantiomer , resolution (logic) , phosphate , ion , chemistry , salt (chemistry) , octahedron , stereochemistry , crystallography , enantioselective synthesis , organic chemistry , biochemistry , computer science , catalysis , artificial intelligence

Easily accessible and configurationally stable are words that describe the enantiopure tris(tetrachlorobenzenediolato)phosphate( V ) ion ( 1 ). These qualities predetermine 1 for use in enantiomeric resolution and asymmetric synthesis. X‐ray structure analysis of the cinchonidinium salt of 1 confirmed the octahedral geometry and provided the absolute configuration of the anion.

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