Structural Rigidity and Luminescence of Chiral Lanthanide Tetraamide Complexes Based on 1,4,7,10‐Tetraazacyclododecane | Zendy

Dickins Rachel S. | Zendy; Howard Judith A. K. | Zendy; Lehmann Christian W. | Zendy; Moloney Janet | Zendy; Parker David | Zendy; Peacock Robert D. | Zendy

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Structural Rigidity and Luminescence of Chiral Lanthanide Tetraamide Complexes Based on 1,4,7,10‐Tetraazacyclododecane

Author(s) -

Dickins Rachel S.,

Howard Judith A. K.,

Lehmann Christian W.,

Moloney Janet,

Parker David,

Peacock Robert D.

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199705211

Subject(s) - terbium , lanthanide , enantiopure drug , europium , luminescence , dota , cationic polymerization , chemistry , ligand (biochemistry) , crystallography , combinatorial chemistry , materials science , stereochemistry , chelation , organic chemistry , enantioselective synthesis , ion , receptor , catalysis , biochemistry , optoelectronics

The enantiopure europium and terbium complexes of the macrocyclic ligand 1 are conformationally rigid in solution. The cationic terbium complex gives rise to an intense circularly polarized emission, which offers much promise for its use as a chiral probe.

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