Transition Metal Germylene Complexes as Hydrogenation Catalysts: The Synthesis of a Rare Bis(amino)germane | Zendy

Litz Kyle E. | Zendy; Bender John E. | Zendy; Kampf Jeff W. | Zendy; Holl Mark M. Banaszak | Zendy

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Transition Metal Germylene Complexes as Hydrogenation Catalysts: The Synthesis of a Rare Bis(amino)germane

Author(s) -

Litz Kyle E.,

Bender John E.,

Kampf Jeff W.,

Holl Mark M. Banaszak

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199704961

Subject(s) - germane , stoichiometry , chemistry , catalysis , transition metal , metal , catalytic hydrogenation , block (permutation group theory) , precious metal , medicinal chemistry , germanium , organic chemistry , combinatorics , mathematics , silicon

Mild conditions avoid the common problem of GeN bond scission in the stoichiometric and catalytic synthesis of a rare example of a stable bis(amino)germane from Group 10 metal–germylene complexes [Eq. (a), R = Et, Ph]. The reaction generates an interesting GeH 2 building block.

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