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Transition Metal Germylene Complexes as Hydrogenation Catalysts: The Synthesis of a Rare Bis(amino)germane
Author(s) -
Litz Kyle E.,
Bender John E.,
Kampf Jeff W.,
Holl Mark M. Banaszak
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199704961
Subject(s) - germane , stoichiometry , chemistry , catalysis , transition metal , metal , catalytic hydrogenation , block (permutation group theory) , precious metal , medicinal chemistry , germanium , organic chemistry , combinatorics , mathematics , silicon
Mild conditions avoid the common problem of GeN bond scission in the stoichiometric and catalytic synthesis of a rare example of a stable bis(amino)germane from Group 10 metal–germylene complexes [Eq. (a), R = Et, Ph]. The reaction generates an interesting GeH 2 building block.