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A Short‐Lived Radical Dication as a Key Intermediate in the Rearrangement of a Persistent Cation: The Oxidative Cyclization of 2,2‐Dimesityl‐1‐(4‐ N,N ‐dimethylaminophenyl)ethenol
Author(s) -
Schmittel Michael,
Langels Anja
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199703921
Subject(s) - dication , chemistry , oxidative phosphorylation , reactive intermediate , radical ion , medicinal chemistry , key (lock) , photochemistry , molecule , ion , organic chemistry , catalysis , biochemistry , biology , ecology
Almost completely unknown —the chemistry of radical dications. A reactive intermediate of this type ( 1 •2+ ) plays a key role in the oxidative rearrangement of the persistent cation 1 + .