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Molecular Cubic Hyperpolarizabilities of Systematically Varied (Triphenylphosphane)–gold‐σ‐Arylalkynyl Complexes
Author(s) -
Whittall Ian R.,
Humphrey Mark G.,
Samoc Marek,
LutherDavies Barry
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199703701
Subject(s) - chromophore , nonlinear optical , schematic , monomer , chemistry , representation (politics) , crystallography , cubic crystal system , nonlinear system , materials science , computational chemistry , chemical physics , photochemistry , organic chemistry , physics , polymer , quantum mechanics , electronic engineering , politics , political science , law , engineering
The largest cubic nonlinear optical activities thus far determined for monomeric organometallic complexes in solution (schematic representation on the right) have been found for alkynyl(triphenylphosphane)gold complexes. In structure–property studies the influence of structural changes in the chromophore on the nonlinear response was systematically investigated.