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A Dinuclear Tin( II ) Amide, a meta ‐Stannylaminocyclophane and Its Orthostannylated Derivative, a Dimeric Trinuclear Tin( II ) Cluster
Author(s) -
Braunschweig Holger,
Drost Christian,
Hitchcock Peter B.,
Lappert Michael F.,
Pierssens Luc J.M.
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199702611
Subject(s) - tin , metalation , equilateral triangle , amide , context (archaeology) , derivative (finance) , cluster (spacecraft) , chemistry , stereochemistry , product (mathematics) , crystallography , organic chemistry , computer science , mathematics , biology , geometry , paleontology , financial economics , economics , programming language
A nearly equilateral triangle is formed by the three Sn atoms in 1 . This complex is the product of a hitherto unknown 2‐stannylation of a 1,3‐diaminobenzene and is thus of general significance in the context of the metalation of arenes. R SiMe 3 .