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Five‐Coordinate Sulfur in a Polymeric Copper( I ) Thiolate Complex
Author(s) -
Parish Richard V.,
Salehi Zahra,
Pritchard Robin G.
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199702511
Subject(s) - copper , sulfur , chemistry , chloride , atom (system on chip) , inorganic chemistry , crystallography , polymer chemistry , organic chemistry , computer science , embedded system
Strong electron‐deficient bonds with four equivalent copper( I ) centers as well as the carbon atom of the organic group are a feature of the thiolate sulfur atoms of the new cage [(CuCl) 12 (SR) 6 ] (R CH 2 CH 2 NH 3 ; structure on the right, Cl and R omitted). This is part of the polymeric complex [Cu 13 Cl 13 (SR) 6 ], which is accessible from cysteamine hydrochloride and copper( I ) chloride. • = Cu, ○ = S.
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